Iron Victory Pillar,Delhi (4th CE). en.wikipedia.org |
Above image: The iron pillar is in the courtyard of Quwwat-ul-Islam Mosque,........
This centuries old pillar has attracted the attention of archaeologists and metallurgists and has been called "a testament to the skill of ancient Indian blacksmiths" because of its high resistance to corrosion. The corrosion resistance results from an even layer of crystalline iron hydrogen phosphate forming on the high phosphorus content iron, which serves to protect it from the effects of the local Delhi climate.
The Iron pillar Delhi, en.wikipedia.org |
R. Balasubramaniam of the IIT, Kanpur explains how the pillar's resistance to corrosion is due to passive protective film at the iron-rust interface. The presence of second-phase particles (slag and un-reduced iron oxides) in the micro structure of the iron, that of high amounts of phosphorus in the metal, and the alternate wetting and drying existing under atmospheric conditions are the three main factors in the three-stage formation of that protective passive film.
Age of the later inscriptions dates to A.D. 1052 -Tomara king Anangpal II. This has suggested by some, without any substantial basis, that the pillar was installed in its current location by Vigraha Rāja, the ruling Tomar king. The pillar is thought to have originally been erected in what is now Udayagiri by one of the Gupta rulers. The suggested age of 402 CE is still a matter of serious discussion
On the Corrosion Resistance of the Delhi Iron Pillar, R. Balasubramaniam, Corrosion Science, Volume 42 (2000) pp. 2103–2129. "Corrosion Science" is a publication specialized in corrosion science and engineering.